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Code Name Synonym
AA-159 H-Phe(4-NH-Poc).HCl H-L-Aph(Poc)-OH // H-L-Phe(4-NH-Poc)-OH // H-4Aph(Poc) // H-L-4Aph(Poc)-OH // H-L-4-Aph(Poc)-OH // H-p-amino-Phe(Poc)-OH // H-L-Phe(4-NH-Pryoc)-OH // H-4Aph(Pryoc) // H-L-4Aph(Pryoc)-OH // H-L-4-Aph(Pryoc)-OH // H-p-amino-Phe(Pryoc)-OH // (1S)‐1‐carboxy‐2‐(4‐{[(prop‐2‐yn‐1‐ yloxy)carbonyl]amino}phenyl)ethan‐1‐aminium chloride
CAS n/a /upload/small/small_aa-159.svg
Formula C13H15ClN2O4
MW 298.7
Purity >98%
Storage +2 ... +8 °C
Note Used as a modified Phe or Tyr analogue in protein and peptide biosynthesis. The Poc-group can be further modified using Click-chemistry.
Code Name Synonym
BO-153 Boc-Phe(4-N3) N-Boc-4-azido-L-phenylalanine // Boc-4-azido-Phe-OH // Boc-p-azido-Phe-OH
CAS 33173-55-6 /upload/more_svg/small/small_bo-153.svg
Formula C14H18N4O4
MW 306.3
Purity >98%
Storage -15 ... -25 °C
Note Boc-Phe(4-N3) can be incorporated into peptides for attachment of functionalities using click-chemistry. DOI:10.1002/anie.200705456; DOI:10.1039/C6TB02848A; This material can also be used to modify graphene sheets by covalent bonding.Chem. Comm. (2010), 46(23), 4097-4099. DOI:10.1039/c001488e.
Code Name Synonym
BO-154 Boc-D-Phe(4-N3) N-Boc-4-azido-D-phenylalanine // Boc-4-azido-D-Phe-OH // Boc-p-azido-D-Phe-OH
CAS 214630-05-4 /upload/more_svg/small/small_bo-154.svg
Formula C14H18N4O4
MW 306.3
Purity >98%
Storage -15 ... -25 °C
Note Boc-D-Phe(4-N3)  can be incorporated into peptides for attachment of functionalities using click-chemistry. Sarkar, Sourav; Libby, Elizabeth A.; Pidgeon, Sean E.; Dworkin, Jonathan; Pires, Marcos M. Angewandte Chemie, International Edition (2016), 55(29), 8401-8404. DOI:10.1002/anie.201603441.
Code Name Synonym
BO-158 Boc-Phe(4-NH-Alloc) Boc-L-Phe(4-NH-Alloc)-OH // Boc-4Aph(Alloc) // Boc-L-4Aph(Alloc)-OH // Boc-L-4-Aph(Alloc)-OH // Boc-p-amino-Phe(Alloc)-OH // Boc-L-Phe(4-NH-Aloc)-OH // Boc-4Aph(Aloc) // Boc-L-4Aph(Aloc)-OH // Boc-L-4-Aph(Aloc)-OH // Boc-p-amino-Phe(Aloc)-OH // (2S)‐2‐{[(tert‐butoxy)carbonyl]amino}‐3‐(4‐{[(prop‐2‐ en‐1‐yloxy)carbonyl]amino}phenyl)propanoic acid // Boc-Phe(p-NHAlloc)
CAS n/a /upload/small/small_bo-158.svg
Formula C18H24N2O6
MW 364.4
Purity >98%
Storage +2 ... +8 °C
Note Used as an orthogonally protected building block in peptide synthesis.
Code Name Synonym
BO-159 Boc-Phe(4-NH-Poc) Boc-L-Aph(Poc)-OH // Boc-L-Phe(4-NH-Poc)-OH // Boc-4Aph(Poc) // Boc-L-4Aph(Poc)-OH // Boc-L-4-Aph(Poc)-OH // Boc-p-amino-Phe(Poc)-OH // Boc-L-Phe(4-NH-Poc)-OH // Boc-4Aph(Pryoc) // Boc-L-4Aph(Pryoc)-OH // Boc-L-4-Aph(Pryoc)-OH // Boc-p-amino-Phe(Pryoc)-OH // (2S)‐2‐{[(tert‐butoxy)carbonyl]amino}‐3‐(4‐{[(prop‐2‐ yn‐1‐yloxy)carbonyl]amino}phenyl)propanoic acid
CAS n/a /upload/small/small_bo-159.svg
Formula C18H22N2O6
MW 362.4
Purity >98%
Storage +2 ... +8 °C
Note Used as an orthogonally protected building block in peptide synthesis. Poc-group can be further modified using Click-chemistry.
Code Name Synonym
FM-252 Fmoc-Phe(4-CH2-N3) Fmoc-L-Phe(4-CH2-N3)-OH // Fmoc-p-azidomethyl-L-phenylalanine // Fmoc-para-methylazido-L-phenylalanine // Fmoc-para-azidomethyl-L-phenylalanine // Fmoc-pN3CH2Phe // Fmoc-pAMF // Fmoc-4-(Azidomethyl)-L-phenylalanine
CAS 2375587-79-2 /upload/small/small_fm-252.svg
Formula C25H22N4O4
MW 442.5
Purity >98%
Storage +2 ... +8 °C
Note This material is used in antibody drug conjugates as a superior SPAAC reaction partner in comparison to H-Phe(4-N3). Bioconjugate Chem. (2014), 25(2), 351-361. DOI:10.1021/bc400490z. It can serve as a vibrational reporter of local protein environments after genetic incorporation into proteins.  J. Phys. Chem. B (2013), 117(30), 8987-8993. DOI:10.1021/jp4052598; Molina, Arturo PCT Int. Appl. (2019), WO 2019023316 A1.
Code Name Synonym
FM-238 Fmoc-D-Phe(4-N3) Fmoc-D-4-azidophenylalanine // Fmoc-4-azido-D-phenylalanine // Fmoc-p-azido-D-Phe-OH // Fmoc-D-Phe(N3)-OH // Fmoc-D-p-azidophenylalanine // Fmoc-D-phenylalanine-azide // (2R)-3-(4-azidophenyl)-2-{[(9H-fluoren-9- ylmethoxy)carbonyl]amino}propanoic acid
CAS 1391586-30-3 /upload/more_svg/small/small_fm-238.svg
Formula C24H20N4O4
MW 428.4
Purity >98%
Storage -15 ... -25 °C
Note Fmoc-D-Phe(4-N3) can be incorporated into peptides for attachment of functionalities using click-chemistry. Sarkar, Sourav; Libby, Elizabeth A.; Pidgeon, Sean E.; Dworkin, Jonathan; Pires, Marcos M. Angewandte Chemie, International Edition (2016), 55(29), 8401-8404. DOI:10.1002/anie.201603441.
Code Name Synonym
FM-251 Fmoc-Phe(4-NH-Alloc) Fmoc-L-Phe(4-NH-Alloc)-OH // Fmoc-4Aph(Alloc) // Fmoc-L-4Aph(Alloc)-OH // Fmoc-L-4-Aph(Alloc)-OH // Fmoc-p-amino-Phe(Alloc)-OH // Fmoc-L-Phe(4-NH-Aloc)-OH // Fmoc-4Aph(Aloc) // Fmoc-L-4Aph(Aloc)-OH // Fmoc-L-4-Aph(Aloc)-OH // Fmoc-p-amino-Phe(Aloc)-OH // Fmoc-Phe(p-NHAlloc)
CAS 220848-55-5 /upload/small/small_fm-251.svg
Formula C28H26N2O6
MW 486.5
Purity >98%
Storage +2 ... +8 °C
Note Used as an orthogonally protected building block in solid-phase peptide synthesis. WO9910312 (A1); Chen, L. et. al. Bioorg. Med. Chem. Lett. 2002, 1679, DOI:10.1016/S0960-894X(02)00201-9; WO2018174078(A1).
Code Name Synonym
FM-250 Fmoc-Phe(4-NH-Poc) Fmoc-L-Aph(Poc)-OH // Fmoc-L-Phe(4-NH-Poc)-OH // Fmoc-4Aph(Poc) // Fmoc-L-4Aph(Poc)-OH // Fmoc-L-4-Aph(Poc)-OH // Fmoc-p-amino-Phe(Poc)-OH // Fmoc-L-Phe(4-NH-Poc)-OH // Fmoc-4Aph(Pryoc) // Fmoc-L-4Aph(Pryoc)-OH // Fmoc-L-4-Aph(Pryoc)-OH // Fmoc-p-amino-Phe(Pryoc)-OH
CAS n/a /upload/small/small_fm-250.svg
Formula C28H24N2O6
MW 484.5
Purity >98%
Storage +2 ... +8 °C
Note Used as an orthogonally protected building block in solid-phase peptide synthesis. Poc-group can be further modified using Click-chemistry.
Code Name Synonym
FM-219 Fmoc-Phe-ACC {7-[(2S)-2-{[(9H-fluoren-9-ylmethoxy)carbonyl]amino}-3-phenylpropanamido]-2-oxochromen-4-yl}acetic acid
CAS 2250437-40-0 /upload/more_svg/small/small_fm-219.svg
Formula C35H28N2O7
MW 588.6
Purity >98%
Storage +2 ... +8 °C

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