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Code Name Synonym
BO-150 Boc-Pro(4-N3)(2R,4R) Boc-(2R,4R)-4-azidoproline // (2R,4R)-4-azido-1-(tert-butoxycarbonyl)pyrrolidine-2- carboxylic acid
CAS 650601-59-5 /upload/more_svg/small/small_bo-150.svg
Formula C10H16N4O4
MW 256.3
Purity >99%
Storage +2 ... +8 °C
Note Boc-Pro(4-N3) is incorporated into peptides and proteins that can be further selectively modified using Staudinger ligation or Click-chemistry. The Azido-group can be reduced to amino-group. J. Med. Chem. (2004), 47(3), 703-710. DOI:10.1021/jm030297m; Chemistry of Materials (2013), 25(22), 4511-4521. DOI:10.1021/cm4020767.
Code Name Synonym
BO-137 Boc-Pro(4-N3) (2S,4S) (2S,4S)-4-azido-1-(tert-butoxycarbonyl)pyrrolidine-2-carboxylic acid // Boc-(2S,4S)-4-azidoproline // Boc-4-azidoproline // Boc-Azp
CAS 132622-65-2 /upload/more_svg/small/small_BO-137.svg
Formula C10H16N4O4
MW 256.3
Purity >99%
Storage +2 ... +8 °C
Code Name Synonym
BO-149 Boc-Pro(4-N3).DCHA (2R, 4S) (2R,4S)-4-azido-1-(tert-butoxycarbonyl)pyrrolidine-2-carboxylic acid // Boc-(2R,4S )-4-azidoproline // Boc-4-azidoproline
CAS 132622-77-6 net /upload/more_svg/small/small_BO-149.svg
Formula C22H39N5O4
MW 437.6
Purity >98%
Storage +2 ... +8 °C
Note Boc-Pro(4-N3) is incorporated into peptides and proteins that can be further selectively modified using Staudinger ligation or Click-chemistry. The Azido-group can be reduced to amino-group. J. Org. Chem. (1991), 56(9), 3009-16. DOI:10.1021/jo00009a016; Bioorg. Med. Chem. Lett. (2003), 13(23), 4241-4244. DOI:10.1016/j.bmcl.2003.07.030.
Code Name Synonym
BO-138 Boc-Pro(4-N3) (2S,4R).DCHA (2S,4R)-4-azido-1-(tert-butoxycarbonyl)pyrrolidine-2-carboxylic acid // Boc-(2S,4R )-4-azidoproline // Boc-4-azidoproline // Boc-Azp
CAS 132622-68-5 net /upload/more_svg/small/small_BO-138.svg
Formula C22H39N5O4
MW 437.6
Purity >98%
Storage +2 ... +8 °C
Note Boc-Pro(4-N3) is incorporated into peptides and proteins that can be further selectively modified using Staudinger ligation or Click-chemistry. The Azido-group can be reduced to amino-group. J. Am. Chem. Soc. (2012), 134(41), 17117-17124. DOI:10.1021/ja3066418; J. Med. Chem. (2012), 55(22), 9856-9867. DOI:10.1021/jm301060g.
Code Name Synonym
BO-156 Boc-Pro(4-NH-Fmoc) (2R,4R) N-Boc-cis-4-N-Fmoc-amino-L-proline // (2R,4R)-N-alpha-Boc-4-(Fmoc-amino)-proline // (4R)-4-N-Fmoc-amino-1-Boc-D-proline // Fmoc-ABPC(2R,4R)-OH // Fmoc(2R,4R)-Abpc // (2R,4R)-N-tert-Butoxycarbonyl-4-N-(9-fluorenylmethoxycarbonyl)aminopyrrolidine-2-carboxylic acid
CAS 1018332-24-5 /upload/svg/small/small/small_bo-156.svg
Formula C25H40N2O6
MW 464.6
Purity >98%
Storage +2 ... +8 °C
Note Boc-Pro(4-NH-Fmoc) (2R,4R) is used in peptide synthesis. DOI:10.1021/jm701214z; JACS (2017), 139(6), 2136-2139. DOI:10.1021/jacs.6b10809; Nature Chemistry (2018), 10(7), 704-714. DOI:10.1038/s41557-018-0033-8.
Code Name Synonym
BO-151 Boc-Pro(4-NH-Fmoc) N-Boc-cis-4-N-Fmoc-amino-L-proline // (2S,4S)-N-alpha-Boc-4-(Fmoc-amino)-proline // (4S)-4-N-Fmoc-amino-1-Boc-L-proline // Fmoc-ABPC(2S,4S)-OH // Fmoc(2S,4S)-Abpc // (2S,4S)-N-tert-Butoxycarbonyl-4-N-(9-fluorenylmethoxycarbonyl)aminopyrrolidine-2-carboxylic acid
CAS 174148-03-9 /upload/more_svg/small/small_bo-151.svg
Formula C25H28N2O6
MW 452.5
Purity >98% (HPLC)
Storage +2 ... +8 °C
Note Boc-Pro(4-NH-Fmoc) is used as a protected 4-amino-Proline building block for peptide synthesis. J. Am. Chem. Soc. (2002), 124(30), 8876-8883. DOI:10.1021/ja020364m; J. Am. Chem. Soc. (2005), 127(26), 9459-9468. DOI:10.1021/ja051648k; Nature Chem. (2018), 10(7), 704-714. DOI:10.1038/s41557-018-0033-8; ACS Chemical Biology (2018), 13(1), 53-59. DOI:10.1021/acschembio.7b00852.
Code Name Synonym
FM-233 Fmoc-Pro(4-NH-Boc) (2S,4R) Fmoc-L-Pro(4-NH-Boc) (4R)
CAS 273222-06-3 /upload/more_svg/small/small_FM-233.svg
Formula C25H28N2O6
MW 452.5
Purity >98%
Storage +2 ... +8 °C
Note Used in solid-phase peptide synthesis. Chem. Comm. (2003), 2606-2607, DOI: 10.1039/B308581C; Sonar, Mahesh V.; Ganesh, Krishna N. Org. Lett. (2010), 12(23), 5390-5393. DOI:10.1021/ol1021993; Usanov, Dmitry L.; Chan, Alix I.; Maianti, Juan Pablo; Liu, David R. Nature Chem. (2018), 10(7), 704-714. DOI:10.1038/s41557-018-0033-8.
Code Name Synonym
FM-231 Fmoc-Pro(4-NH-Boc) (2S,4S) (4S)-4-tert-butylyloxycarbonylamino-1-(9-fluorenylmethyloxycarbonyl)-L-proline // Fmoc-Pro(4-NH-Boc)-OH (2S,4S)
CAS 221352-74-5 /upload/small/small_fm-231.svg
Formula C25H28N2O6
MW 452.5
Purity >98%
Storage +2 ... +8 °C
Note Used in solid-phase peptide synthesis. Chem. Comm. (2003), 2606-2607, DOI: 10.1039/B308581C. Angew. Chem. Int. Ed. (2014), 53(32), 8367-8371. DOI:10.1002/anie.201403780; PCT Int. Appl. (2014), WO 2014151634 A1; Nature Chem. (2018), 10(7), 704-714. DOI:10.1038/s41557-018-0033-8.
Code Name Synonym
BO-045 Boc-D-Thz Boc-Thz(S) // Boc-D-thiazolidine-4-carboxylic acid // Boc-D-thioproline
CAS 63091-82-7 /upload/more_svg/small/small_BO-045.svg
Formula C9H15NO4S
MW 233.3
Purity >99%
Storage +2 ... +8 °C
Code Name Synonym
DD-150 H-Dap(Boc) H-Dapa(Boc)-OH // H-Dpr(Boc)-OH // N-beta-Boc-L-2,3-diaminopropionic acid
CAS 74536-29-1 /upload/more_svg/small/small_DD-150.svg
Formula C8H16N2O4
MW 204.2
Purity >98%
Enantiopurity >99.9%
Storage +2 ... +8 °C

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