Fmoc-Lys(N3-Aca-DIM)

Synonyms
(2S)‐6‐{[6‐azido‐1‐(4,4‐dimethyl‐2,6‐ dioxocyclohexylidene)hexyl]amino}‐2‐({[(9H‐fluoren‐9‐ yl)methoxy]carbonyl}amino)hexanoic acid // Fmoc-Lysine(Dimedone-azidocaproyl)

ID

FM-255

Formula

C35H43N5O6

CAS

2408993-39-3

MW

629.8

Purity

>98%

Storage

-15 ... -25 °C

Product image

References

Used as a SPPS bulding-block for the “helping hand” strategy for purification of highly insoluble peptides. Solubilising residues are attached to the Lys side-chains using Click-chemistry. The solubilising tag can be removed with 1M hydrazine or hydroxylamine solution. Kay, M.S.; Aucagne, V. J. Am. Chem. Soc. 2016, 11775. DOI: 10.1021/jacs.6b05719; Chou, D. H-C. Org. Biomol. Chem. 2019, 1703. DOI: 10.1039/c8ob01212a.

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