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Fmoc-D-Dap(Ns)

Synonyms
Fmoc-D-Dapa(Ns)-OH // Fmoc-D-Dpr(Ns)-OH // Fmoc-D-Dap(Ns)-OH // Fmoc-D-Dap(Nosyl) // (2R)‐2‐({[(9H‐fluoren‐9‐yl)methoxy]carbonyl}amino)‐3‐ (2‐nitrobenzenesulfonamido)propanoic acid // N-alpha-Fmoc-N-beta-Ns-D-2,3-diaminopropionic acid

ID	DD-198
Formula	C24H21N3O8S
CAS	487027-90-7
MW	511.5
Purity	>98%
Storage	+2 ... +8 °C

References

Used as an orthogonally protected Dap building-block in SPPS. The Nosyl-group can be utilised to enable Mitsunobu-reaction or N-alkylations at the side-chain N atom. Goodman, M. et al J. Org. Chem. (2002), 67(25), 8820-8826, DOI:10.1021/jo020447l; Monfregola, L.; De Luca, S.Amino Acids (2011), 41(4), 981-990, DOI:10.1007/s00726-010-0798-6; De Luca, S.; Della Moglie, R.; De Capua, A.; Morelli, G. Tetrahedron Lett. (2005), 46(39), 6637-6640, DOI:10.1016/j.tetlet.2005.07.154.

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