Fmoc-Aeg(Dde)

Synonyms
Dde-Aeg(Fmoc) // Fmoc-N-(2-Dde-aminoethyl)-glycine // Fmoc-N-(2-Dde-aminoethyl)-Gly-OH // Fmoc-N-(N-β-Dde-aminoethyl)-Gly-OH

ID

PN-015

Formula

C29H32N2O6
 

CAS

n/a

MW

504.6

Purity

>98%

Storage

+2 to +8 °C

Product image

References

Building block for preparation of protected PNA (Peptide Nucleic Acid) monomers.

For selective Dde-cleavage please refer to this information: The best results in terms of reactivity and selectivity were achieved using a mixture of NH2OH*HCl/imidazole in NMP/CH2Cl2. After 3 h, the Dde group was cleaved cleanly while the Fmoc group was completely stable, yielding Dde-deprotected material as the only material with a quantitative yield.

Bradley, M. et. al. Org. Lett., 2004, 1127.

https://doi.org/10.1021/ol049905y

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